I personally don't think Live Chat is a good means of support. It's great for sales, don't get me wrong. You can answer pre-sales questions quick and close a sale in no time. But.. when it comes to actual technical support for your clients, Live Chat and Phone are not the best tools to use at all. In support tickets your clients are able to copy and paste actual error messages and other information that is helpful and not easily repeated over the phone.
And although your clients can copy and paste things in Live Chat, it still not good for support, as many support requests require you to investigate more to find the problem, and this leads to your clients in Live Chat waiting for your response (usually more than 10 mins..) as I've seen with so many hosts. Then, you're probably going to be asked to open a ticket to the support department anyways. So, in short...
Live Chat For Pre-Sales =
Live Chat For Support =
